I cannot say for sure if she can marry again however I suspect she can. Record keeping in Thailand is not as it is in the developed countries.
However I would still recommend that your fiancee get the divorce. I solves a couple problems. First it unties him from the legal aspect of marriage allowing him to marry again if he wishes and secondly it unties him from the psycological effect of knowing he is still married. It will allow him to move on with his life.
If you wish more info on this, please post your e-mail and I will respond more off the forum.
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